PHOTO-REACTIVE ACRYLIC-ALKYD COMPOSITION WITH BIOCIDE ADDITIVE FOR WOOD PROTECTION COATING DEVELOPMENT
Abstract
Introduction. The study of photo-reactive varnishes can serve as a basis for choosing alternatives in the restoration and preservation of historical and cultural heritage sites. Purpose of the study: The study aimed to explore the possibility of using photoreactive acrylic-alkyd composition with biocide additive as a paint and varnish material in construction as well as restoration and preservation. Methods. The possibility of obtaining protective thick-layer coatings from the proposed compositions with a thickness up to 80 μm without compromising polymerization efficiency in the layer was demonstrated by express Raman spectroscopy. Results. The coatings obtained by UV-curing from the composition with vinylated alkyd oligomers were tested to analyze vapor permeability, hardness, and hydrophobicity. The resistance of the specimens coated with the developed compounds against a mixture of mold fungi was studied. Aspergillus, Chaetomium, Trichoderma and Penicillium fungi were used as strains of micromycetes as those most infesting the open surfaces of timber. The effectiveness of biocide additive in the amount of 0.24 wt % is shown. The developed photo-reactive varnishes make it possible to form a finished wood coating within 1–2 minutes.
Keywords
Full Text:
PDFReferences
Anikina, N. A. and Smirnov, V. F. (2013). A study of resistance of some acrylic polymers to microscopic fungi. Bulletin of Lobachevsky State University of Nizhni Novgorod, No. 6 (1), pp. 142–145.
Anikina, N. A., Smirnov, V. F., Kryazhev, D. V., Smirnova, O. N., Zakharova, E. A., and Grigor’eva, E. N. (2014). Investigation of the resistance of paints and varnishes used in construction, instrumentation and mechanical engineering to microscopic fungi. Bulletin of Lobachevsky State University of Nizhni Novgorod, No. 2 (1), pp. 100–105.
Babkin, O. E., Babkina, L. A., Aykasheva, O. S., and Il’ina, V. V. (2019). Principles of composition of recipes, determining the properties of photo-polymer coatings and articles. Bulletin of the Saint Petersburg State Institute of Technology (Technical University), No. 48 (74), pp. 63–67.
Babkin, O. E., Babkina, L. A., Aykasheva, O. S., Il’ina, V. V., and Vlasov, M. Yu. (2022). UV curing technology. Theory and practice. Bulletin of the Saint Petersburg State Institute of Technology (Technical University), No. 62 (88), pp. 6–11. DOI: 10.36807/1998-9849-2022-62-88-12-15.
Babkin, O. E., Babkina, L. A., Aykasheva, O. S., and Ilyina, V. V. (2020). Physical-chemical grounds for preparation of formulae of liquid photopolymerized compounds for wide application. Part 1. Influence of monomer nature. Adhesives. Sealants. Technologies, No. 5, pp. 20–26. DOI: 10.31044/1813-7008-2020-0-5-20-26.
Babkin, O. E., Babkina, L. A., Il’Ina, V. V., and Aykasheva, O. S. (2021). Photo-curable varnishes for architectural construction and restoration. Russian Coatings Journal, No. 11, pp. 30–34.
Babkin, O. E., Babkina, L. A., Letunovich, O. A., and Yatsenko, I. A. (2014). Vinylalkyd coatings UV-curing. Russian Coatings Journal, No. 5, pp. 61–63.
Babkin, O. E., Il’ina, V. V., Babkina, L. A., and Sirotinina, M. V. (2016). UV-cured coatings for functional protection. Russian Journal of Applied Chemistry, Vol. 89, Issue 1, pp. 114–119. DOI: 10.1134/S1070427216010183.
Chisholm, B. J., Cawse, J. N., Molaison, C. A., and Brennan, M. J. Jr. (2006). Patent US6998425B2. UV curable coating compositions and uses thereof.
Drinberg, A. S. (2014). Vinylated alkyd oligomers. Moscow: LKM-Press, 152 p.
Feng, R., Han, R., and Zhang, B. (2023). Ultraviolet curable materials for 3D printing soft robots: from hydrogels to elastomers and shape memory polymers. In: Yang, H., Liu, H., Zou, J., Yin, Z., Liu, L., Yang, G., Ouyang, X., Wang, Z. (eds.). Intelligent Robotics and Applications. ICIRA 2023. Lecture Notes in Computer Science, Vol. 14270. Singapore: Springer, pp. 12–21. DOI: 10.1007/978-981-99-6492-5_2.
Ge, Q., Chen, Z., Cheng, J., Zhang, B., Zhang, Y.-F., Li, H., He, X., Yuan, C., Liu, J., Magdassi, S., and Qu, S. (2021). 3D printing of highly stretchable hydrogel with diverse UV curable polymers. Science Advances, Vol. 7, No. 2, eaba4261. DOI: 10.1126/sciadv.aba4261.
Il’ina, V. V. and Strokova, V. V. (2023). Photopolymer materials in the practice of restoration and conservation works on objects of historical and cultural value. Construction Materials, No. 12, pp. 76–83. DOI: 10.31659/0585-430X-2023-820-12-76-83.
Kondrashov, E. K. and Kozlova, A. A. (2022a). UV-quantum technologies of formation protective, decorative and functional polymer coatings. Part I. Film-forming agents of UV-polymerized coatings. Russian Coatings Journal, No. 7–8 (546), pp. 20–26.
Kondrashov, E. K. and Kozlova, A. A. (2022b). UV-quantum technologies of formation protective, decorative and functional polymer coatings. Part II. Pigments, fillers, additives and compositions for UV-curable coatings. Russian Coatings Journal, No. 9 (547), pp. 14–20.
Mazanik, N. V. and Snopkov, V. B. (2009). Test-cultures of fungi for testing wood protection products. Proceedings of BSTU. No. 2. Forest and Woodworking Industry, No. 2, pp. 194–198.
Novakov, I. A., Chalykh, A. E., Nistratov, A. V., Frolova, V. I., Khasbiullin, R. R., and Klimov, V. V. (2011). Study of the influence of polysulfide oligomers in compositions based on oligoacrylates on the structure formation and properties of photocured materials. Plasticheskie Massy, No. 4, pp. 12–15.
Novikova, S. I. and Chizhova, M. A. (2019). Protection of paints and coatings from biodeterioration. Interactive Science, No. 2 (36), pp. 39–42. DOI: 10.21661/r-473689.
Petrov, N. S. (2023). Technology and modern market of UV-materials. Russian Coatings Journal, No. 5 (554), pp. 12–19.
Poth, U. (2009). Polyesters and alkyd resins. Moscow: Paint-Media, 232 p.
Ruskol, I. Yu., Alekseeva, E. I., Skripnichenko, L. A., Babin, A. N., Kitaeva, N. S., and Shvets, N. I. (2008). Optically transparent photo-curable organosilicon compositions. Polymer Science, Series D, Vol. 1, Issue 3, pp. 207–211. DOI: 10.1134/S1995421208030155.
Skorokhodov, V. D. and Shestakova, S. I. (2004). Protection of non-metallic building materials against biocorrosion. Moscow: Vysshaya Shkola, 204 p.
Susorov, I. A. and Babkin, O. E. (2015). Analysis of patterns in synthesis of oligomeric and high molecular weight compounds using chain polymerization method. Saint Petersburg: Saint Petersburg State University of Film and Television, 236 p.
Yakhontova, V. I. (1988). Paints and varnishes based on modified alkyd resins. Moscow: Research Institute for Technical and Economic Studies in the Chemical Complex, 45 p.
Refbacks
- There are currently no refbacks.